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Accepted version

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2015-09-03

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/154520

Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition

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https://doi.org/10.1039/C5CC07073B

Abstract

The first example of phototunable SMMs has been reported. Upon UV irradiation, variations of the coordination sphere around Dy(III) ions actually affect the magnetic behaviour of the compound via [2+2] cycloaddition reaction, leading to a magnetic transformation from the SMM behaviour to a field-induced slow relaxation.

Subject

Terres rares, Imants, Magnetisme, Fotoquímica

Subject (English)

Rare earths, Magnets, Magnetism, Photochemistry

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Articles publicats en revistes (Química Inorgànica i Orgànica)

Citation

WANG, Long-Fei, et al. Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition. Chemical Communications. 2015. Vol. 51, num. 84, pags. 15358-15361. ISSN 1359-7345. [consulted: 7 of June of 2026]. Available at: https://hdl.handle.net/2445/154520

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