Heterometallic Co-Dy SMMs grafted on iron oxide nanoparticles

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dc.contributor.authorRosado Piquer, Lidia
dc.contributor.authorDreiser, Jan
dc.contributor.authorSañudo Zotes, Eva Carolina
dc.date.accessioned2021-07-21T11:35:01Z
dc.date.issued2021-07-10
dc.date.updated2021-07-21T11:35:01Z
dc.description.abstractHeterometallic 3d-4f SMM [Co4Dy(OH)2(SALOH)5(chp)4(MeCN)(H2O)2] (1) has been deposited onto iron oxide nanoparticles (NPs) with an oleate self-assembled monolayer (SAM) as a surfactant. The obtained hybrid molecular-inorganic system 1-NP has been thoroughly characterized. The oleate SAM separates SMM 1 from the magnetic substrate to avoid the strong-coupling between the surface and molecule to ensure that 1 retains its magnetic properties in 1-NP. The magnetic properties of the hybrid system 1-NP have been characterized by element specific XMCD: the heterometallic SMM retains its magnetic properties on the surface of the iron oxide NPs while there is an enhancement of the magnetic properties of the NPs.
dc.format.extent9 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec713194
dc.identifier.issn1477-9226
dc.identifier.urihttps://hdl.handle.net/2445/179265
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/d1dt01519b
dc.relation.ispartofDalton Transactions, 2021, vol. 50, p. 9589-9597
dc.relation.urihttps://doi.org/10.1039/d1dt01519b
dc.rights(c) Rosado Piquer, Lidia et al., 2021
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationNanopartícules
dc.subject.classificationÒxid de ferro
dc.subject.classificationPropietats magnètiques
dc.subject.otherNanoparticles
dc.subject.otherFerric oxide
dc.subject.otherMagnetic properties
dc.titleHeterometallic Co-Dy SMMs grafted on iron oxide nanoparticles
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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