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Article

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Accepted version

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2016-04-11

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/152577

Exploiting metallophilicity for the assembly of inorganic nanocrystals and conjugated organic molecules

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https://doi.org/10.1002/cphc.201600239

Abstract

The accurate engineering of interfaces between inorganic nanocrystals and semiconducting organic molecules is currently viewed as key for further developments in critical fields such as photovoltaics and photocatalysis. In this work, a new and unconventional source of interface interaction based on metal-metal bonds is presented. With this aim, an AuI organometallic gelator was exploited for the formation of hydrogellike nanocomposites containing inorganic nanoparticles and conjugated organic molecules. Noteworthy, the establishment of metallophilic interactions at the interface between the two moieties greatly enhances interparticle coupling in the composites. Thus, we believe that this new hybrid system might represent a promising alternative in several fields, such as in the fabrication of improved light-harvesting devices.

Subject

Or, Nanopartícules

Subject (English)

Gold, Nanoparticles

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Articles publicats en revistes (Química Inorgànica i Orgànica)

Citation

DALMASES SOLÉ, Mariona, et al. Exploiting metallophilicity for the assembly of inorganic nanocrystals and conjugated organic molecules. Chemphyschem. 2016. Vol. 17, num. 2190-2196. ISSN 1439-4235. [consulted: 12 of August of 2026]. Available at: https://hdl.handle.net/2445/152577

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