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2016-04-11

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Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/152577

Exploiting metallophilicity for the assembly of inorganic nanocrystals and conjugated organic molecules

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https://doi.org/10.1002/cphc.201600239

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The accurate engineering of interfaces between inorganic nanocrystals and semiconducting organic molecules is currently viewed as key for further developments in critical fields such as photovoltaics and photocatalysis. In this work, a new and unconventional source of interface interaction based on metal-metal bonds is presented. With this aim, an AuI organometallic gelator was exploited for the formation of hydrogellike nanocomposites containing inorganic nanoparticles and conjugated organic molecules. Noteworthy, the establishment of metallophilic interactions at the interface between the two moieties greatly enhances interparticle coupling in the composites. Thus, we believe that this new hybrid system might represent a promising alternative in several fields, such as in the fabrication of improved light-harvesting devices.

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Or, Nanopartícules

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Gold, Nanoparticles

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Articles publicats en revistes (Química Inorgànica i Orgànica)

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DALMASES SOLÉ, Mariona, AGUILÓ LINARES, Elisabet, LLORCA, Jordi, RODRÍGUEZ RAURELL, Laura, FIGUEROLA I SILVESTRE, Albert. Exploiting metallophilicity for the assembly of inorganic nanocrystals and conjugated organic molecules. _Chemphyschem_. 2016. Vol. 17, núm. 2190-2196. [consulta: 23 de gener de 2026]. ISSN: 1439-4235. [Disponible a: https://hdl.handle.net/2445/152577]

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