Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands

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dc.contributor.authorOrgué Gassol, Sílvia
dc.contributor.authorFlores-Gaspar, Areli
dc.contributor.authorBiosca, Maria
dc.contributor.authorPàmies, Oscar
dc.contributor.authorDiéguez, Montserrat
dc.contributor.authorRiera i Escalé, Antoni
dc.contributor.authorVerdaguer i Espaulella, Xavier
dc.date.accessioned2015-12-04T10:43:32Z
dc.date.issued2015-10-02
dc.date.updated2015-12-04T10:43:32Z
dc.description.abstractThe stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.
dc.format.extent4 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec654578
dc.identifier.issn1359-7345
dc.identifier.pmid26477668
dc.identifier.urihttps://hdl.handle.net/2445/68334
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofReproducció del document publicat a: http://dx.doi.org/10.1039/c5cc07504a
dc.relation.ispartofChemical Communications, 2015, vol. 51, p. 17548-17551
dc.relation.urihttp://dx.doi.org/10.1039/c5cc07504a
dc.rightscc by (c) Orgué Gassol, Sílvia et al., 2015
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationHidròlisi
dc.subject.classificationLligands
dc.subject.classificationCatàlisi asimètrica
dc.subject.classificationCompostos de bor
dc.subject.otherHydrolysis
dc.subject.otherLigands
dc.subject.otherEnantioselective catalysis
dc.subject.otherBoron compounds
dc.titleStereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion

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