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Polarized supramolecular aggregates based on luminescent perhalogenated gold derivatives
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Reaction of [Au(C6F5)(tht)] (tht = tetrahydrothiophene) with 1,3,5-triaza-7-phosphaadamantane (PTA) and 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]-nonane (DAPTA) leads to the formation of [Au(C6F5)(phosph)] (phosph = PTA, 1; phosph = DAPTA, 2). The compounds are slightly soluble in water and aggregate at higher concentrations giving rise to the formation of needle- and rod-like structures (1) and well-organized spherical aggregates (2). Compounds 1 and 2 were reacted with AgPF6 giving rise to the formation in all cases of luminescent water soluble 1:1 Au·Ag heterometallic complexes, as evidenced by X-ray crystal structure determination. The use of different silver salts that differ on the counterion induces changes on the resulting luminescence and aggregation morphology.
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GAVARA, Raquel, PINTO MARTÍNEZ, Andrea, DONAMARÍA, Rocío, OLMOS, M. elena, LÓPEZ DE LUZURIAGA, José m., RODRÍGUEZ RAURELL, Laura. Polarized supramolecular aggregates based on luminescent perhalogenated gold derivatives. _Inorganic Chemistry_. 2017. Vol. 56, núm. 19, pàgs. 11946-11955. [consulta: 18 de febrer de 2026]. ISSN: 0020-1669. [Disponible a: https://hdl.handle.net/2445/156718]