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2013

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/46043

Versatile methodology to hydrate alkynes, in the presence of a wide variety of functional groups, with Mercury(II) p-Toluensulfonamidate, under catalytic, mild and neutral conditions

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http://dx.doi.org/10.1080/00397911.2012.686003

Abstract

A method to generate carbonylic compounds from alkynes under mild and neutral conditions, with excellent functional group compatibility and high yields, is described. Hydration takes place under catalytic conditions by using from 0.1 to 0.2 equivalents of the easily available and inexpensive mercury(II) p-toluensulfonamidate in a hydroalcoholic solution. After use the catalyst is iner tized and/or recycled ...

Subject

Compostos carbonílics, Química orgànica

Subject (English)

Carbonyl compounds, Organic chemistry

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Articles publicats en revistes (Química Inorgànica i Orgànica)

Citation

COROMINAS, Albert (Corominas Tarruella) and MONTAÑA PEDRERO, Ángel-Manuel. Versatile methodology to hydrate alkynes, in the presence of a wide variety of functional groups, with Mercury(II) p-Toluensulfonamidate, under catalytic, mild and neutral conditions. Synthetic Communications. 2013. Vol. 43, num. 15, pags. 2062-2072. ISSN 0039-7911. [consulted: 9 of August of 2026]. Available at: https://hdl.handle.net/2445/46043

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