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Crinine-type alkaloids from Hippeastrum aulicum and H. calyptratum
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An ongoing search for alkaloids in the Amaryllidaceae species using GC MS resulted in the identification of two crinine-type alkaloids, aulicine (1) and 3-O-methyl-epimacowine, (2) from the indigenous Brazilian species Hippeastrum aulicum and Hippeastrum calyptratum, respectively. In addition, two alkaloids, 11-oxohaemanthamine (3) and 7-methoxy-O-methyllycorenine (4) were both isolated from H. aulicum. Furthermore, we provide here complete NMR spectroscopic data for the homolycorine analogues nerinine (5) and albomaculine (6). The absolute stereochemistry of the 5,10b-ethano bridge in the crinine variants was determined by circular dichroism and X-ray crystallographic analysis, thus presenting the first direct evidence for the presence of crinine-type alkaloids in the genus Hippeastrum.
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DE ANDRADE, Jean Paulo, et al. Crinine-type alkaloids from Hippeastrum aulicum and H. calyptratum. Phytochemistry. 2014. Vol. 103, num. 188-195. ISSN 0031-9422. [consulted: 3 of August of 2026]. Available at: https://hdl.handle.net/2445/169248