NMR signal enhancement of > 50 000 times in fast dissolution dynamic nuclear polarization

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dc.contributor.authorPinto, L.F.
dc.contributor.authorMarín Montesinos, Ildefonso
dc.contributor.authorLloveras, Vega
dc.contributor.authorMuñoz-Gómez, José Luis
dc.contributor.authorPons Vallès, Miquel
dc.contributor.authorVeciana, Jaume
dc.contributor.authorVidal Gancedo, José
dc.date.accessioned2019-07-30T12:01:53Z
dc.date.available2019-07-30T12:01:53Z
dc.date.issued2017-03-03
dc.date.updated2019-07-30T12:01:53Z
dc.description.abstractHerein, we report the synthesis and the study of a novel mixed biradical with BDPA and TEMPO radical units that are covalently bound by an ester group (BDPAesterTEMPO) as a polarizing agent for fast dissolution DNP. The biradical exhibits an extremely high DNP NMR enhancement of >50 000 times, which constitutes one of the largest signal enhancements observed so far, to the best of our knowledge
dc.format.extent4 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec670961
dc.identifier.issn1359-7345
dc.identifier.urihttps://hdl.handle.net/2445/138591
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/c7cc00635g
dc.relation.ispartofChemical Communications, 2017, vol. 53, num. 26, p. 3757-3760
dc.relation.urihttps://doi.org/10.1039/c7cc00635g
dc.rights(c) Pinto, L.F. et al., 2017
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationPolarització (Física nuclear)
dc.subject.classificationSpin (Física nuclear)
dc.subject.otherPolarization (Nuclear physics)
dc.subject.otherNuclear spin
dc.titleNMR signal enhancement of > 50 000 times in fast dissolution dynamic nuclear polarization
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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