Chiral Oxazolidine Complexes Derived from Phenolic Schiff Bases

Vista senzilla d'ítem
dc.contributor.authorMayans Ayats, Júlia
dc.contributor.authorGómez, Daniel
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.contributor.authorEscuer Fité, Albert
dc.date.accessioned2021-03-23T12:19:41Z
dc.date.available2021-05-04T05:10:25Z
dc.date.issued2020-05-04
dc.date.updated2021-03-23T12:19:41Z
dc.description.abstractSchiff bases derived from pyridyl- or salicyl-aldehydes and aminoalcohols can evolve to heterocyclic oxazolidines, which in the presence of cations allow the formation of uncommon coordination compounds. In this work, we report new NiII and mixed valence MnII/ MnIV complexes derived from pyridyl oxazolidines and the unprecedented characterization of enantiomerically pure oxazolidines derived from the condensation of o-vanillin with phenylglycinol in the presence of NiII cations. The different reactivity of the pyridinic or phenolic Schiff bases has been compared, and the new systems have been structurally, optically, and magnetically characterized.
dc.format.extent34 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec709622
dc.identifier.issn1528-7483
dc.identifier.urihttps://hdl.handle.net/2445/175629
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.cgd.0c00466
dc.relation.ispartofCrystal Growth & Design, 2020, vol. 20, num. 6, p. 4176-4184
dc.relation.urihttps://doi.org/10.1021/acs.cgd.0c00466
dc.rights(c) American Chemical Society , 2020
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.subject.classificationPropietats magnètiques
dc.subject.classificationAlcohols
dc.subject.classificationLligands (Bioquímica)
dc.subject.otherMagnetic properties
dc.subject.otherAlcohols
dc.subject.otherLigands (Biochemistry)
dc.titleChiral Oxazolidine Complexes Derived from Phenolic Schiff Bases
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

Fitxers

Paquet original

Mostrant 1 - 1 de 1
Miniatura
Nom:
709622.pdf
Mida:
758.74 KB
Format:
Adobe Portable Document Format
Descarregar

Col·leccions

Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)