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Article

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Accepted version

Publication date

2009

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/173196

An Unexpected Oxidation in the Generation of Cyclopenta[c]piperidines by Ring-Closing Metathesis

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Related resource

https://doi.org/10.1021/ol901704f

Abstract

Ring-closing metathesis reaction of dienes A (n= 1, R= CO2R') leads to fused cyclopentenones C instead of the expected cyclopentene derivatives B. RCM reaction of the other dienes A takes place satisfactorily, affording the expected fused cycloalkene derivatives B. Cyclohexene B (n= 2, R= CO2R') also undergoes oxidation to the corresponding cyclohexenone C.

Subject

Lactames, Alcaloides, Compostos bioactius, Química orgànica

Subject (English)

Lactams, Alkaloids, Bioactive compounds, Organic chemistry

Citation

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Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
Articles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia)

Citation

AMAT TUSÓN, Mercedes, et al. An Unexpected Oxidation in the Generation of Cyclopenta[c]piperidines by Ring-Closing Metathesis. Organic Letters. 2009. Vol. 11, num. 4370-4373. ISSN 1523-7060. [consulted: 8 of June of 2026]. Available at: https://hdl.handle.net/2445/173196

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