An Unexpected Oxidation in the Generation of Cyclopenta[c]piperidines by Ring-Closing Metathesis

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dc.contributor.authorAmat Tusón, Mercedes
dc.contributor.authorBrunaccini, Elisa
dc.contributor.authorCheca Castaño, Begoña
dc.contributor.authorPérez Bosch, Maria
dc.contributor.authorLlor Brunés, Núria
dc.contributor.authorBosch Cartes, Joan
dc.date.accessioned2021-01-18T07:08:53Z
dc.date.available2021-01-18T07:08:53Z
dc.date.issued2009
dc.date.updated2021-01-18T07:08:53Z
dc.description.abstractRing-closing metathesis reaction of dienes A (n= 1, R= CO2R') leads to fused cyclopentenones C instead of the expected cyclopentene derivatives B. RCM reaction of the other dienes A takes place satisfactorily, affording the expected fused cycloalkene derivatives B. Cyclohexene B (n= 2, R= CO2R') also undergoes oxidation to the corresponding cyclohexenone C.
dc.format.extent4 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec571419
dc.identifier.issn1523-7060
dc.identifier.urihttps://hdl.handle.net/2445/173196
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/ol901704f
dc.relation.ispartofOrganic Letters, 2009, vol. 11, p. 4370-4373
dc.relation.urihttps://doi.org/10.1021/ol901704f
dc.rights(c) American Chemical Society , 2009
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
dc.subject.classificationLactames
dc.subject.classificationAlcaloides
dc.subject.classificationCompostos bioactius
dc.subject.classificationQuímica orgànica
dc.subject.otherLactams
dc.subject.otherAlkaloids
dc.subject.otherBioactive compounds
dc.subject.otherOrganic chemistry
dc.titleAn Unexpected Oxidation in the Generation of Cyclopenta[c]piperidines by Ring-Closing Metathesis
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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