Four New Trinuclear {Cu3(μ3-OH)(oximate)3}2+ Clusters: Crystal Structure and Magnetic Behavior
| dc.contributor.author | Speed, S. | |
| dc.contributor.author | Font Bardia, Ma. Mercedes | |
| dc.contributor.author | El Fallah El Boufrahi, Mohamed Salah | |
| dc.contributor.author | Vicente Castillo, Ramón | |
| dc.date.accessioned | 2020-07-09T12:40:55Z | |
| dc.date.available | 2020-07-09T12:40:55Z | |
| dc.date.issued | 2014-09 | |
| dc.date.updated | 2020-07-09T12:40:55Z | |
| dc.description.abstract | Four new triangular copper(II) complexes with the fragment {Cu3(μ3-OH)(oximate)3}2+ and formulae [Cu3(μ3-OH)(μ-Cl)(Py2CNO)3(tBuPO3H)]·4H2O (1), [Cu3(μ3-OH)(μ-Br)(Py2CNO)3(tBuPO3H)]·3.5H2O (2), [Cu3(μ3-OH)(μ-Br)(PhPyCNO)3(tBuPO3H)(MeOH)]·1.5 MeOH (3), [Cu3(μ3-OH)Cl2(PhPyCNO)3]·0.5H2O (4), (Py2CNO = di(2-pyridyl)ketoximate, PhPyCNO = phenyl(2-pyridyl)ketoximate, tBuPO3H2 = tert-butylphosphonic acid) are reported. The magnetic properties of compounds 1-4 were studied. The compounds were found to exhibit strong antiferromagnetic coupling and antisymmetric exchange interaction. | |
| dc.format.extent | 34 p. | |
| dc.format.mimetype | application/pdf | |
| dc.identifier.idgrec | 644536 | |
| dc.identifier.issn | 1477-9226 | |
| dc.identifier.uri | https://hdl.handle.net/2445/168257 | |
| dc.language.iso | eng | |
| dc.publisher | Royal Society of Chemistry | |
| dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/c4dt02215g | |
| dc.relation.ispartof | Dalton Transactions, 2014, vol. 43, p. 16919-16927 | |
| dc.relation.uri | https://doi.org/10.1039/c4dt02215g | |
| dc.rights | (c) Speed, S. et al., 2014 | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | |
| dc.subject.classification | Estructura cristal·lina (Sòlids) | |
| dc.subject.classification | Magnetisme | |
| dc.subject.other | Layer structure (Solids) | |
| dc.subject.other | Magnetism | |
| dc.title | Four New Trinuclear {Cu3(μ3-OH)(oximate)3}2+ Clusters: Crystal Structure and Magnetic Behavior | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/acceptedVersion |
Fitxers
Paquet original
1 - 1 de 1