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Article

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Accepted version

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2014-12-22

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/108386

Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines

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https://doi.org/10.1039/c4cc09106j

Abstract

In non-coordinating solvents, borane was shown to be an efficient directing group for the stereoselective 1,2-addition of organolithium reagents to P-stereogenic N-phosphanylimines. Selectivity was reversed in coordinating solvents. This process can lead to novel ligand scaffolds for asymmetric catalysis.

Subject

Compostos organometàl·lics, Lligands (Bioquímica), Catàlisi asimètrica

Subject (English)

Organometallic compounds, Ligands (Biochemistry), Enantioselective catalysis

Citation

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Articles publicats en revistes (Química Inorgànica i Orgànica)

Citation

FLORES-GASPAR, Areli, et al. Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines. Chemical Communications. 2014. Vol. 51, num. 1941-1944. ISSN 1359-7345. [consulted: 9 of August of 2026]. Available at: https://hdl.handle.net/2445/108386

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