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Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines

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dc.contributor.authorFlores-Gaspar, Areli
dc.contributor.authorOrgué Gassol, Sílvia
dc.contributor.authorGrabulosa, Arnald
dc.contributor.authorRiera i Escalé, Antoni
dc.contributor.authorVerdaguer i Espaulella, Xavier
dc.date.accessioned2017-03-14T08:59:50Z
dc.date.available2017-03-14T08:59:50Z
dc.date.issued2014-12-22
dc.date.updated2017-03-14T08:59:50Z
dc.description.abstractIn non-coordinating solvents, borane was shown to be an efficient directing group for the stereoselective 1,2-addition of organolithium reagents to P-stereogenic N-phosphanylimines. Selectivity was reversed in coordinating solvents. This process can lead to novel ligand scaffolds for asymmetric catalysis.
dc.format.extent4 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec646126
dc.identifier.issn1359-7345
dc.identifier.urihttps://hdl.handle.net/2445/108386
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/c4cc09106j
dc.relation.ispartofChemical Communications, 2014, vol. 51, p. 1941-1944
dc.relation.urihttps://doi.org/10.1039/c4cc09106j
dc.rights(c) Flores-Gaspar, Areli et al., 2014
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationCompostos organometàl·lics
dc.subject.classificationLligands (Bioquímica)
dc.subject.classificationCatàlisi asimètrica
dc.subject.otherOrganometallic compounds
dc.subject.otherLigands (Biochemistry)
dc.subject.otherEnantioselective catalysis
dc.titleBorane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimineseng
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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