Chiral Versus Non-Chiral [MnIII6MnIINaI], [MnIII6MnII2NaI2] and [MnIII 3MnIINaI] Clusters Derived from Schiff Bases or the Fight for Symmetry

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dc.contributor.authorPilichos, Evangelos
dc.contributor.authorEscuer Fité, Albert
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.contributor.authorMayans Ayats, Júlia
dc.date.accessioned2021-03-23T12:29:46Z
dc.date.available2021-12-31T06:10:21Z
dc.date.issued2020
dc.date.updated2021-03-23T12:29:46Z
dc.description.abstractThe reaction in basic media of manganese chloride with Schiff bases derived from the condensation of ovanillin with different chiral/racemic aminoalcohols yielded in a family of complexes in which the nuclearity, symmetry and magnetic behavior is controlled by changing the position of the chiral carbon. Chiral and racemic clusters with [MnIII6MnIINaI], [MnIII6MnII2NaI 2] and [MnIII3MnIINaI] metallic core have been structurally and magnetically characterized. The racemic clusters with an odd number of chiral ligands exhibit the anomalous mixing of ligands with different conformation. Related racemic compounds have been reviewed.
dc.format.extent11 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec709623
dc.identifier.issn1434-1948
dc.identifier.urihttps://hdl.handle.net/2445/175631
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1002/chem.202001656
dc.relation.ispartofEuropean Journal of Inorganic Chemistry, 2020, vol. 26, num. 57, p. 13053-13062
dc.relation.urihttps://doi.org/10.1002/chem.202001656
dc.rights(c) Wiley-VCH, 2020
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.subject.classificationQuiralitat
dc.subject.classificationPropietats magnètiques
dc.subject.classificationManganès
dc.subject.classificationQuímica supramolecular
dc.subject.otherChirality
dc.subject.otherMagnetic properties
dc.subject.otherManganese
dc.subject.otherSupramolecular chemistry
dc.titleChiral Versus Non-Chiral [MnIII6MnIINaI], [MnIII6MnII2NaI2] and [MnIII 3MnIINaI] Clusters Derived from Schiff Bases or the Fight for Symmetry
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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