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703401.pdf (5.65 MB)

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2020-08-09

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cc-by (c) Ejarque, Daniel et al., 2020
Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/174206

Construction of Zn(II) Linear Trinuclear Secondary Building Units from A Coordination Polymer Based on α-Acetamidocinnamic Acid and 4-Phenylpyridine

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Recurs relacionat

https://doi.org/10.3390/molecules25163615

Resum

The synthesis and characterization of one coordination polymer and two trinuclear complexes are presented. The coordination polymer [Zn2( -O,O'-ACA)2(ACA)2(4-Phpy)2]n (1) has been obtained by the reaction between Zn(OAc)2 2H2O, -acetamidocinnamic acid (HACA), and 4-phenylpyridine (4-Phpy) using EtOH as solvent. Its recrystallization in CH3CN or EtOH yields two trinuclear complexes, both having pinwheel arrays with formulas [Zn3( -ACA)6(4-Phpy)2] 4CH3CN (2 4CH3CN) and [Zn3( -ACA)6(EtOH)2] 4EtOH (3 4EtOH), respectively. These trinuclear species, unavoidably lose their solvent co-crystallized molecules at RT yielding the complexes [Zn3( -ACA)6(4-Phpy)2] (2) and [Zn3( -ACA)6(EtOH)2] (3). In addition, compound 2 has also been obtained reacting Zn(OAc)2 2H2O, HACA, and 4-Phpy in a 1:2:2 ratio using CH3CN as solvent. Compounds 1-3 have been characterized by analytical and spectroscopic techniques. Furthermore, single crystals suitable for X-ray di raction method for compounds 1, 2 4CH3CN, and 3 4EtOH were obtained and their supramolecular interactions have been studied and discussed, showing 2D supramolecular planes for the trinuclear complexes and a 3D supramolecular network for the coordination polymer. Finally, the supramolecular interactions of 2 4CH3CN and 3 4EtOH have been compared using Hirshfeld surface analysis and electrostatic potential calculations.

Matèries

Polímers, Cristalls moleculars

Matèries (anglès)

Polymers, Molecular crystals

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Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
Articles publicats en revistes (Centres Científics i Tecnològics de la Universitat de Barcelona (CCiTUB))

Citació

EJARQUE, Daniel, et al. Construction of Zn(II) Linear Trinuclear Secondary Building Units from A Coordination Polymer Based on α-Acetamidocinnamic Acid and 4-Phenylpyridine. Molecules. 2020. Vol. 25, num. 16. ISSN 1420-3049. [consulted: 4 of August of 2026]. Available at: https://hdl.handle.net/2445/174206

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