Synthesis, crystal structures and properties of cis- and trans-isomers of [Pt{C6H4-4R1-1-[C8H4N-30-NOMe]}Cl2(dmso)] (R1 = H or Cl)
| dc.contributor.author | López Martínez, Ma. Concepción | |
| dc.contributor.author | Moya Álvarez, Carlos | |
| dc.contributor.author | Basu, Pradipta K. | |
| dc.contributor.author | González Gazulla, Asensio | |
| dc.contributor.author | Solans-Monfort, Xavier | |
| dc.contributor.author | Font Bardia, Ma. Mercedes | |
| dc.contributor.author | Calvet Pallàs, Maria Teresa | |
| dc.contributor.author | Lalinde, Elena | |
| dc.contributor.author | Moreno, M. Teresa | |
| dc.date.accessioned | 2024-11-27T08:14:21Z | |
| dc.date.available | 2024-11-27T08:14:21Z | |
| dc.date.issued | 2011-07-27 | |
| dc.date.updated | 2024-11-27T08:14:21Z | |
| dc.description.abstract | The study of the reactivity of the 3-methoxyimino-2-phenyl-3H-indoles C6H4-4R1-1-[C8H4N-30-NOMe] [R1 = Cl (1a) or H (1b)] with cis-[PtCl2(dmso)2] has allowed the isolation of trans-[Pt{C6H4-4R1-1- [C8H4N-30-NOMe]}Cl2(dmso)] [R1 = Cl (2a) or H (2b)] and cis-[Pt{C6H4-4R1-1-[C8H4N-30-NOMe]}Cl2(dmso)] CH2Cl2 [R1 = Cl (3a) or H(3b)]. Their crystal structures confirm: (a) the existence of a PtANindole bond, (b) the relative arrangement of the Cl ligands (trans in 2a and 2b or cis in 3a and 3b) and (c) the anti- (E) configuration of the oxime. A comparative study of the spectroscopic and photo-optical properties of ligands and their platinum(II) complexes (2a, 2b, 3a and 3b) is also reported. | |
| dc.format.extent | 37 p. | |
| dc.format.mimetype | application/pdf | |
| dc.identifier.idgrec | 597819 | |
| dc.identifier.issn | 0022-2860 | |
| dc.identifier.uri | https://hdl.handle.net/2445/216765 | |
| dc.language.iso | eng | |
| dc.publisher | Elsevier B.V. | |
| dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.molstruc.2011.05.030 | |
| dc.relation.ispartof | Journal of Molecular Structure, 2011, vol. 999, num.1-3, p. 49-59 | |
| dc.relation.uri | https://doi.org/10.1016/j.molstruc.2011.05.030 | |
| dc.rights | (c) Elsevier B.V., 2011 | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | |
| dc.subject.classification | Cristal·lografia | |
| dc.subject.classification | Luminescència | |
| dc.subject.classification | Platí | |
| dc.subject.other | Crystallography | |
| dc.subject.other | Luminescence | |
| dc.subject.other | Platinum | |
| dc.title | Synthesis, crystal structures and properties of cis- and trans-isomers of [Pt{C6H4-4R1-1-[C8H4N-30-NOMe]}Cl2(dmso)] (R1 = H or Cl) | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/acceptedVersion |
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