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2018-06-14

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/127958

General and stereoselective aminoxylation of biradical titanium(IV) enolates with TEMPO: a detailed study on the effect of the chiral auxiliary

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https://doi.org/10.1039/c8ob01074a

Abstract

A comprehensive analysis of the influence of the chiral auxiliary on the α-aminoxylation of titanium(IV) enolates with TEMPO indicated that (S) 4-tert-butyl-1-oxazolidine-2-thione is the most appropriate scaffold to provide a single diastereomer in high yields for a variety of substrates, which converts such a radical reaction into a highly chemo- and stereoselective oxidation

Subject

Titani, Estereoquímica

Subject (English)

Titanium, Stereochemistry

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Articles publicats en revistes (Química Inorgànica i Orgànica)

Citation

KENNINGTON, Stuart C. D., et al. General and stereoselective aminoxylation of biradical titanium(IV) enolates with TEMPO: a detailed study on the effect of the chiral auxiliary. Organic & Biomolecular Chemistry. 2018. Vol. 16, num. 4807-4815. ISSN 1477-0520. [consulted: 20 of August of 2026]. Available at: https://hdl.handle.net/2445/127958

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