General and stereoselective aminoxylation of biradical titanium(IV) enolates with TEMPO: a detailed study on the effect of the chiral auxiliary

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dc.contributor.authorKennington, Stuart C. D.
dc.contributor.authorGómez Palomino, Alejandro
dc.contributor.authorSalomó i Prat, Ernest
dc.contributor.authorRomea, Pedro
dc.contributor.authorUrpí Tubella, Fèlix
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.date.accessioned2019-02-06T10:57:36Z
dc.date.available2019-06-14T05:10:20Z
dc.date.issued2018-06-14
dc.date.updated2019-02-06T10:57:36Z
dc.description.abstractA comprehensive analysis of the influence of the chiral auxiliary on the α-aminoxylation of titanium(IV) enolates with TEMPO indicated that (S) 4-tert-butyl-1-oxazolidine-2-thione is the most appropriate scaffold to provide a single diastereomer in high yields for a variety of substrates, which converts such a radical reaction into a highly chemo- and stereoselective oxidation
dc.format.extent10 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec681138
dc.identifier.issn1477-0520
dc.identifier.pmid29915837
dc.identifier.urihttps://hdl.handle.net/2445/127958
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/c8ob01074a
dc.relation.ispartofOrganic & Biomolecular Chemistry, 2018, vol. 16, p. 4807-4815
dc.relation.urihttps://doi.org/10.1039/c8ob01074a
dc.rights(c) Kennington, Stuart C. D. et al., 2018
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationTitani
dc.subject.classificationEstereoquímica
dc.subject.otherTitanium
dc.subject.otherStereochemistry
dc.titleGeneral and stereoselective aminoxylation of biradical titanium(IV) enolates with TEMPO: a detailed study on the effect of the chiral auxiliary
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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