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Decanedioic acid (C10H18O4) - Dodecanedioic acid (C12H22O4) system: polymorphism of the components and experimental phase diagram
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The experimental temperature/composition phase diagram of the binary system decanedioic acid (C10H18O4)/dodecanedioic acid (C12H22O4) was established by combining X-ray powder diffraction (XRD), differential-scanning calorimetry (DSC), infrared spectroscopy (IR), scanning electron microscopy (SEM), and thermo-optical microscopy (TOM). Both compounds crystallize in the same ordered form, C (P21/c), which is the phase that melts in both cases. The C form melts in C12H22O4 earlier than in C10H18O4 , in contrast to other unbranched-chain compounds (alkanes, alkanols, and alkanoic acids) in which the melting temperatures increase as the C-atom number rises. Contrary to what might be expected, total solid-state miscibility is not observed. The C10H18O4/C12H22O4 binary system shows a complex phase diagram. At low temperatures, a new monoclinic form, Ci (P21/c), stabilizes as a result of the disorder of composition in the mixed samples; two [C þ Ci] domains appear. Upon heating, four solid - solid and seven solid - liquid domains appear related by eutectic and peritectic invariants. All the crystallographic forms observed are isostructural.
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VENTOLÀ, L., et al. Decanedioic acid (C10H18O4) - Dodecanedioic acid (C12H22O4) system: polymorphism of the components and experimental phase diagram. Helvetica Chimica Acta. 2008. Vol. 91, num. 7, pags. 1286-1298. ISSN 0018-019X. [consulted: 10 of October of 2026]. Available at: https://hdl.handle.net/2445/160417