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2018-09-01

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/162672

Chiral [MnIIMnIII3M'] (M' = NaI, CaII, MnII) and [MnIIMnIII6NaI2] clusters built from an enantiomerically pure Schiff base: synthetic, chiroptical and magnetic properties

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https://doi.org/10.1002/chem.201803730

Abstract

From the reaction of manganese halides with the chiral Schiff bases obtained by condensation of o-vanillin and (R)- or (S)-phenylglycinol, 11 complexes based on pentanuclear cages with trigonal bipyramidal [MnIIMnIII3M'] (M'=NaI, CaII, MnII) or enneanuclear [MnIIMnIII6NaI2] cores were synthesized. Structural, supramolecular chirality, and optical properties were explored. The magnetic properties of related systems were reviewed, and the magnetic response of the new systems was rationalized to the bond parameters.

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Quiralitat, Propietats magnètiques, Manganès

Subject (English)

Chirality, Magnetic properties, Manganese

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Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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MAYANS AYATS, Júlia, et al. Chiral [MnIIMnIII3M'] (M' = NaI, CaII, MnII) and [MnIIMnIII6NaI2] clusters built from an enantiomerically pure Schiff base: synthetic, chiroptical and magnetic properties. Chemistry-A European Journal. 2018. Vol. 24, num. 18705-18717. ISSN 0947-6539. [consulted: 7 of June of 2026]. Available at: https://hdl.handle.net/2445/162672

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