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Diastereoselective and catalytic α-alkylation of chiral N-acyl thiazolidinethiones with stable carbocationic salts

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dc.contributor.authorKennington, Stuart C. D.
dc.contributor.authorFerré, Laura
dc.contributor.authorRomo Fernández, Juan Manuel
dc.contributor.authorRomea, Pedro
dc.contributor.authorUrpí Tubella, Fèlix
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.date.accessioned2019-03-04T15:22:32Z
dc.date.available2019-03-04T15:22:32Z
dc.date.issued2017-06-15
dc.date.updated2019-03-04T15:22:32Z
dc.description.abstractDirect nickel-catalyzed alkylation of chiral N-acyl-4-isopropyl-1,3-thiazolidine-2-thiones using a commercially available nickel(II) complex, (Me3P)2NiCl2, has been developed for tropylium and trityl tetrafluoroborate salts. The reaction provides a single diastereomer of the corresponding adducts in good to high yields, which, in turn, can be easily converted into a wide array of enantiomerically pure compounds that are difficult to obtain by other asymmetric procedures.
dc.format.extent8 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec672779
dc.identifier.issn0022-3263
dc.identifier.pmid28525716
dc.identifier.urihttps://hdl.handle.net/2445/129477
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.joc.7b00657
dc.relation.ispartofJournal of Organic Chemistry, 2017, vol. 82, num. 12, p. 6426-6433
dc.relation.urihttps://doi.org/10.1021/acs.joc.7b00657
dc.rights(c) American Chemical Society , 2017
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationCatàlisi
dc.subject.classificationNíquel
dc.subject.classificationQuiralitat
dc.subject.otherCatalysis
dc.subject.otherNickel
dc.subject.otherChirality
dc.titleDiastereoselective and catalytic α-alkylation of chiral N-acyl thiazolidinethiones with stable carbocationic salts
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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