Reductive Elimination from Cyclometalated Platinum(IV) Complexes To Form Csp2−Csp3 Bonds and Subsequent Competition between Csp2−H and Csp3−H Bond Activation

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dc.contributor.authorCrespo Vicente, Margarita Ma.
dc.contributor.authorAnderson, Craig M.
dc.contributor.authorKfoury, Nicole
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.contributor.authorCalvet Pallàs, Maria Teresa
dc.date.accessioned2024-05-07T12:54:17Z
dc.date.available2024-05-07T12:54:17Z
dc.date.issued2012
dc.date.updated2024-05-07T12:54:22Z
dc.description.abstract<p>Reductive elimination reactions of the cyclometalated platinum(IV) compounds [PtMe2Br{C6H4CH NCH2(4-ClC6H4)}L] (L = SMe2, PPh3) to form Csp3−Csp2 bonds, followed by either exclusive Csp2−H bond activation (L = SMe2) or competition between Csp2−H and Csp3−H bond activation (L = PPh3) are reported. Reductive elimination to form a C−Br bond is also reported.</p>
dc.format.extent17 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec620881
dc.identifier.issn0276-7333
dc.identifier.urihttps://hdl.handle.net/2445/210984
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/om300303a
dc.relation.ispartofOrganometallics, 2012, vol. 31, num.12, p. 4401-4404
dc.relation.urihttps://doi.org/10.1021/om300303a
dc.rights(c) American Chemical Society, 2012
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationLligands
dc.subject.classificationHidrocarburs
dc.subject.otherLigands
dc.subject.otherHydrocarbons
dc.titleReductive Elimination from Cyclometalated Platinum(IV) Complexes To Form Csp2−Csp3 Bonds and Subsequent Competition between Csp2−H and Csp3−H Bond Activation
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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