Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate

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dc.contributor.authorEsquius, G.
dc.contributor.authorPons, Josefina
dc.contributor.authorYáñez, R.
dc.contributor.authorRos, Josep
dc.contributor.authorSolans, Xavier, 1949-2007
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.date.accessioned2020-05-14T07:19:10Z
dc.date.available2020-05-14T07:19:10Z
dc.date.issued2002
dc.date.updated2020-05-14T07:19:11Z
dc.description.abstractIn the title compound, [Rh2(C8H15N3)2(C8H12)2]Cl2·CH2Cl2·CH3OH, the dinuclear RhI complex has C2 symmetry and the two pyrazolato ligands act as [mu]-bridges. The coordination of each RhI cation is completed by one cyclo­octa­diene (COD) ligand. It is shown that the average Rh-C(COD) distance is linearly dependent on the Rh-N(pyrazole) distance in this type of compound, and this is ascribed to the steric hindrance produced by the packing.
dc.format.extent2 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec563147
dc.identifier.issn0108-2701
dc.identifier.urihttps://hdl.handle.net/2445/160142
dc.language.isoeng
dc.publisherInternational Union of Crystallography
dc.relation.isformatofReproducció del document publicat a: https://doi.org/10.1107/S0108270101020017
dc.relation.ispartofActa Crystallographica Section C: Crystal Structure Communications, 2002, num. 58, p. m133-m134
dc.relation.urihttps://doi.org/10.1107/S0108270101020017
dc.rights(c) International Union of Crystallography, 2002
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.subject.classificationCristal·lografia
dc.subject.otherCrystallography
dc.titleBis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion

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