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2015-04-27

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/159723

Negatively charged metallacarborane redox couples with both members stable to air

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https://doi.org/10.1002/chem.201406244

Abstract

It was possible to synthesize and isolate redox couples in which both partners are negatively charged. The handy framework is [3,3'-Co(1,2-closo-C2B9H11)2]-. The E½ potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3'-Co(1,2-closo-C2B9H7I4)2]- is the most favorable as it is isolatable and stable in air.

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Cobalt, Reacció d'oxidació-reducció

Subject (English)

Cobalt, Oxidation-reduction reaction

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Articles publicats en revistes (Química Inorgànica i Orgànica)

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LUPU, Marius, et al. Negatively charged metallacarborane redox couples with both members stable to air. Chemistry-A European Journal. 2015. Vol. 21, num. 18, pags. 6888-6897. ISSN 0947-6539. [consulted: 6 of June of 2026]. Available at: https://hdl.handle.net/2445/159723

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