Tipus de document

Article

Versió

Versió acceptada

Data de publicació

Tots els drets reservats

Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/159723

Negatively charged metallacarborane redox couples with both members stable to air

Títol de la revista

Director/Tutor

Contribució addicional

ISSN de la revista

Títol del volum

Resum

It was possible to synthesize and isolate redox couples in which both partners are negatively charged. The handy framework is [3,3'-Co(1,2-closo-C2B9H11)2]-. The E½ potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3'-Co(1,2-closo-C2B9H7I4)2]- is the most favorable as it is isolatable and stable in air.

Citació

Citació

LUPU, Marius, et al. Negatively charged metallacarborane redox couples with both members stable to air. Chemistry-A European Journal. 2015. Vol. 21, num. 18, pags. 6888-6897. ISSN 0947-6539. [consulted: 28 of September of 2026]. Available at: https://hdl.handle.net/2445/159723

Exportar metadades

JSON - METS

Compartir registre