Negatively charged metallacarborane redox couples with both members stable to air

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dc.contributor.authorLupu, Marius
dc.contributor.authorZaulet, Adnana
dc.contributor.authorTeixidor, Francesc
dc.contributor.authorRuiz Sabín, Eliseo
dc.contributor.authorViñas, Clara
dc.date.accessioned2020-05-12T10:09:43Z
dc.date.available2020-05-12T10:09:43Z
dc.date.issued2015-04-27
dc.date.updated2020-05-12T10:09:43Z
dc.description.abstractIt was possible to synthesize and isolate redox couples in which both partners are negatively charged. The handy framework is [3,3'-Co(1,2-closo-C2B9H11)2]-. The E½ potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3'-Co(1,2-closo-C2B9H7I4)2]- is the most favorable as it is isolatable and stable in air.
dc.format.extent10 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec653202
dc.identifier.issn0947-6539
dc.identifier.urihttps://hdl.handle.net/2445/159723
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1002/chem.201406244
dc.relation.ispartofChemistry-A European Journal, 2015, vol. 21, num. 18, p. 6888-6897
dc.relation.urihttps://doi.org/10.1002/chem.201406244
dc.rights(c) Wiley-VCH, 2015
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationCobalt
dc.subject.classificationReacció d'oxidació-reducció
dc.subject.otherCobalt
dc.subject.otherOxidation-reduction reaction
dc.titleNegatively charged metallacarborane redox couples with both members stable to air
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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