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Article

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Accepted version

Publication date

2019-07-01

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/162075

Decanuclear FeIII clusters with hemiacetal ligands: a new{M10(μ3-O)8} cluster core

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https://doi.org/10.1039/c9dt01568j

Abstract

The characterization of a decanuclear FeIII cluster with α-methyl- 2-pyridinemethanolate, generated by the hydrolysis of Schiff bases, inspired us to carry out an initial exploration of the direct syntheses of medium nuclearity FeIII clusters starting from aldehydes in methanolic medium. The new complexes exhibit an unprecedented {Fe10(μ3-O)8} cluster core.

Subject

Lligands (Bioquímica), Hidròlisi, Compostos organometàl·lics

Subject (English)

Ligands (Biochemistry), Hydrolysis, Organometallic compounds

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Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

Citation

MAYANS AYATS, Júlia, et al. Decanuclear FeIII clusters with hemiacetal ligands: a new{M10(μ3-O)8} cluster core. Journal of the Chemical Society. Dalton Transactions. Vol.  2019, num. 48, pags. 35. ISSN 1472-7773. [consulted: 8 of August of 2026]. Available at: https://hdl.handle.net/2445/162075

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