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Dimerization of highly pyramidalized 3,4,8,9-tetramethyltetracyclo[4.4.0.03,9.04,8]dec-1(6)-ene to a hydrocarbon featuring four cyclohexane rings in boat conformation

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dc.contributor.authorRey Carrizo, Matías
dc.contributor.authorBarniol-Xicota, Marta
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.contributor.authorVázquez Cruz, Santiago
dc.date.accessioned2020-06-14T12:24:57Z
dc.date.available2020-06-14T12:24:57Z
dc.date.issued2014-05-26
dc.date.updated2020-06-14T12:24:58Z
dc.description.abstractThe synthesis, chemical trapping, and dimerization of a highly pyramidalized alkene is reported. Its dimer is a unique nonacycle featuring three planar cyclobutane rings, four cyclopentane rings, and four cyclohexane rings in boat conformations. The X-ray diffraction analysis showed a H-H distance between the flagpole hydrogen atoms of 1.999 and a separation of 2.619 between the two flagpole carbon atoms. The three cyclobutane rings of the dimer were thermally stable
dc.format.extent17 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec641512
dc.identifier.issn1433-7851
dc.identifier.urihttps://hdl.handle.net/2445/165457
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1002/anie.201403985
dc.relation.ispartofAngewandte Chemie-International Edition, 2014, vol. 53, num. 31, p. 8195-8199
dc.relation.urihttps://doi.org/10.1002/anie.201403985
dc.rights(c) Wiley-VCH, 2014
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.subject.classificationCompostos policíclics
dc.subject.classificationAlquens
dc.subject.classificationHidrocarburs
dc.subject.otherPolycyclic compounds
dc.subject.otherAlkenes
dc.subject.otherHydrocarbons
dc.titleDimerization of highly pyramidalized 3,4,8,9-tetramethyltetracyclo[4.4.0.03,9.04,8]dec-1(6)-ene to a hydrocarbon featuring four cyclohexane rings in boat conformation
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)