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Anionic guests in prismatic cavities generated by enneanuclear nickel metallacycles

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The combination of polydentate aminated ligands with the 2-pyridyloxime-nickel-azide system leads to series of clusters with unprecedented topologies. Among them, a remarkable family of {Ni9} metallacycles that are capable of selective encapsulation of azide/halide anions in a cryptand-like cavity through hydrogen-bond interactions has been characterized.

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ESTEBAN JARNE, Jordi, FONT BARDIA, Ma. Mercedes and ESCUER FITÉ, Albert. Anionic guests in prismatic cavities generated by enneanuclear nickel metallacycles. Inorganic Chemistry. 2014. Vol. 53, num. 2, pags. 1113-1121. ISSN 0020-1669. [consulted: 24 of June of 2026]. Available at: https://hdl.handle.net/2445/165279

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