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2014

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/165279

Anionic guests in prismatic cavities generated by enneanuclear nickel metallacycles

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https://doi.org/10.1021/ic402651k

Abstract

The combination of polydentate aminated ligands with the 2-pyridyloxime-nickel-azide system leads to series of clusters with unprecedented topologies. Among them, a remarkable family of {Ni9} metallacycles that are capable of selective encapsulation of azide/halide anions in a cryptand-like cavity through hydrogen-bond interactions has been characterized.

Subject

Anions, Lligands, Compostos de coordinació, Magnetisme nuclear, Níquel

Subject (English)

Anions, Ligands, Coordination compounds, Nuclear magnetism, Nickel

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Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

Citation

ESTEBAN JARNE, Jordi, FONT BARDIA, Ma. Mercedes and ESCUER FITÉ, Albert. Anionic guests in prismatic cavities generated by enneanuclear nickel metallacycles. Inorganic Chemistry. 2014. Vol. 53, num. 2, pags. 1113-1121. ISSN 0020-1669. [consulted: 6 of June of 2026]. Available at: https://hdl.handle.net/2445/165279

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