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Accepted version

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2016-08-18

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/153817

Designed intramolecular blocking of the spin crossover of an Fe(II) complex

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https://doi.org/10.1039/c6dt03047e

Abstract

A ligand derived from 1,3bpp (2-(pyrazol-1-yl)-6-(pyrazol-3-yl)-pyridine) has been prepared to prove that the spin crossover (SCO) of an Fe(II) complex can be blocked by means of intramolecular interactions not related to the crystal field. Calculations show that the blocking is caused by the energy penalty incurred by the rotation of a phenyl ring, needed to avoid steric hindrance upon SCO.

Subject

Ferro, Lligands, Química supramolecular

Subject (English)

Iron, Ligands, Supramolecular chemistry

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Articles publicats en revistes (Química Inorgànica i Orgànica)

Citation

BARTUAL-MURGUI, Carlos, et al. Designed intramolecular blocking of the spin crossover of an Fe(II) complex. Dalton Transactions. 2016. Vol. 45, num. 36, pags. 14058-14062. ISSN 1477-9226. [consulted: 8 of August of 2026]. Available at: https://hdl.handle.net/2445/153817

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