Designed intramolecular blocking of the spin crossover of an Fe(II) complex

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dc.contributor.authorBartual-Murgui, Carlos
dc.contributor.authorVela Llausí, Sergi
dc.contributor.authorRoubeau, Olivier
dc.contributor.authorAromí Bedmar, Guillem
dc.date.accessioned2020-03-25T10:00:47Z
dc.date.available2020-03-25T10:00:47Z
dc.date.issued2016-08-18
dc.date.updated2020-03-25T10:00:48Z
dc.description.abstractA ligand derived from 1,3bpp (2-(pyrazol-1-yl)-6-(pyrazol-3-yl)-pyridine) has been prepared to prove that the spin crossover (SCO) of an Fe(II) complex can be blocked by means of intramolecular interactions not related to the crystal field. Calculations show that the blocking is caused by the energy penalty incurred by the rotation of a phenyl ring, needed to avoid steric hindrance upon SCO.
dc.format.extent5 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec667418
dc.identifier.issn1477-9226
dc.identifier.urihttps://hdl.handle.net/2445/153817
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/c6dt03047e
dc.relation.ispartofDalton Transactions, 2016, vol. 45, num. 36, p. 14058-14062
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/258060/EU//FUNCMOLQIP
dc.relation.urihttps://doi.org/10.1039/c6dt03047e
dc.rights(c) Bartual-Murgui, C et al., 2016
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationFerro
dc.subject.classificationLligands
dc.subject.classificationQuímica supramolecular
dc.subject.otherIron
dc.subject.otherLigands
dc.subject.otherSupramolecular chemistry
dc.titleDesigned intramolecular blocking of the spin crossover of an Fe(II) complex
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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