Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone

Abstract

Calcite veins precipitated in the Estamariu thrust during two tectonic events decipher the temporal and spatial relationships between deformation and fluid migration in a long-lived thrust and determine the influence of basement rocks on the fluid chemistry during deformation. Structural and petrological observations constrain the timing of fluid migration and vein formation, whilst geochemical analyses (δ13C, δ18O, 87Sr/86Sr, clumped isotope thermometry and elemental composition) 15 of the related calcite cements and host rocks indicate the fluid origin, pathways and extent of fluid-rock interaction. The first tectonic event, recorded by calcite cements Cc1a and Cc2, is related to the Alpine reactivation of the Estamariu thrust, and is characterized by the migration of meteoric fluids, heated at depth (temperatures between 56 and 98 ºC) and interacted with crystalline basement rocks before upflowing through the thrust zone. During the Neogene extension, the Estamariu thrust was reactivated and normal faults and shear fractures with calcite cements Cc3, Cc4 and Cc5 developed. Cc3 and Cc4 precipitated 20 from hydrothermal fluids (temperatures between 127 and 208 ºC and between 102 and 167 ºC, respectively) derived from crystalline basement rocks and expelled through fault zones during deformation. Cc5 precipitated from low temperature meteoric waters percolating from the surface through small shear fractures. The comparison between our results and already published data in other structures from the Pyrenees suggests that regardless of the origin of the fluids and the tectonic context, basement rocks have a significant influence on the fluid chemistry, particularly on the 87Sr/86Sr ratio. Accordingly, the cements 25 precipitated from fluids interacted with crystalline basement rocks have significantly higher 87Sr/86Sr ratios (> 0.710) with respect to those precipitated from fluids that have interacted with the sedimentary cover (< 0.710).