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Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/217061
Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems
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A new family of lanthanide compounds has been synthesized using 1,2-bis(diphenylphosphino)ethane dioxide (dppeO2) as an O-donor ligand through the phosphoryl group to lanthanide(III) cations and structurally, magnetically and optically studied. Depending on the lanthanide, two different topologies appear: the two-dimensional structure [LnIII(dppeO2)1.5(NO3)3(H2O)0.5]n (Ln = Ce (1), Sm (2) and Dy (6)) and the one-dimensional structure [Ln(dppeO2)(NO3)3DMF]n (Ln = Eu (3), Gd (4) and Tb (5)). Some of the Ln-derived complexes have been used as structural probes, while others have been synthesized to use the specific characteristics of each cation to take advantage of their magnetic/luminescence properties. Complex 6 presents slow relaxation of the magnetization while 2, 3 and 5 present emitting properties in the visible range.
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PILICHOS, Evangelos, et al. Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems. Dalton Transactions. 2023. Vol. 52, num. 8, pags. 2485-2494. ISSN 1477-9226. [consulted: 24 of June of 2026]. Available at: https://hdl.handle.net/2445/217061