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Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems

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dc.contributor.authorPilichos, Evangelos
dc.contributor.authorTubau Ribot, Ànnia
dc.contributor.authorSpeed Castro, Saskia
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.contributor.authorEscuer Fité, Albert
dc.contributor.authorGrabulosa, Arnald
dc.contributor.authorMayans Ayats, Júlia
dc.date.accessioned2024-12-12T17:53:56Z
dc.date.available2024-12-12T17:53:56Z
dc.date.issued2023-01-25
dc.date.updated2024-12-12T17:53:56Z
dc.description.abstractA new family of lanthanide compounds has been synthesized using 1,2-bis(diphenylphosphino)ethane dioxide (dppeO2) as an O-donor ligand through the phosphoryl group to lanthanide(III) cations and structurally, magnetically and optically studied. Depending on the lanthanide, two different topologies appear: the two-dimensional structure [LnIII(dppeO2)1.5(NO3)3(H2O)0.5]n (Ln = Ce (1), Sm (2) and Dy (6)) and the one-dimensional structure [Ln(dppeO2)(NO3)3DMF]n (Ln = Eu (3), Gd (4) and Tb (5)). Some of the Ln-derived complexes have been used as structural probes, while others have been synthesized to use the specific characteristics of each cation to take advantage of their magnetic/luminescence properties. Complex 6 presents slow relaxation of the magnetization while 2, 3 and 5 present emitting properties in the visible range.
dc.format.extent10 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec736795
dc.identifier.issn1477-9226
dc.identifier.urihttps://hdl.handle.net/2445/217061
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofReproducció del document publicat a: https://doi.org/10.1039/d2dt03621e
dc.relation.ispartofDalton Transactions, 2023, vol. 52, num.8, p. 2485-2494
dc.relation.urihttps://doi.org/10.1039/d2dt03621e
dc.rightscc-by (c) Pilichos, Evangelos et al., 2023
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationRadiocristal·lografia
dc.subject.classificationPropietats magnètiques
dc.subject.classificationÒptica
dc.subject.otherX-ray crystallography
dc.subject.otherMagnetic properties
dc.subject.otherOptics
dc.titleMagnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion

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