New topologies in pentanuclear nickel/oximato clusters: structural and magnetic characterization
| dc.contributor.author | Esteban Jarne, Jordi | |
| dc.contributor.author | Font Bardia, Ma. Mercedes | |
| dc.contributor.author | Sánchez Costa, José | |
| dc.contributor.author | Teat, Simon J. | |
| dc.contributor.author | Escuer Fité, Albert | |
| dc.date.accessioned | 2020-06-12T07:04:03Z | |
| dc.date.available | 2020-06-12T07:04:03Z | |
| dc.date.issued | 2014 | |
| dc.date.updated | 2020-06-12T07:04:03Z | |
| dc.description.abstract | In the present work, five new Ni5 clusters employing the versatile 2-pyridylcyanoxime ligand have been synthesized and chemically, structurally, and magnetically characterized. The crystallographic examination of these Ni5 clusters together with those already published in the literature, giving a total number of 14 complexes, exhibiting up to 8 different topologies for which the relationship between topology, reaction conditions and magnetic response has been analyzed. DC magnetic measurements were carried in the 300-2 K range for the new complexes and the analysis of the experimental data revealed an antiferromagnetic response for the oximato mediated interactions with a variety of ground states (S = 0, 1, 3) as function of the cluster topology. | |
| dc.format.extent | 36 p. | |
| dc.format.mimetype | application/pdf | |
| dc.identifier.idgrec | 634889 | |
| dc.identifier.issn | 0020-1669 | |
| dc.identifier.uri | https://hdl.handle.net/2445/165286 | |
| dc.language.iso | eng | |
| dc.publisher | American Chemical Society | |
| dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/ic500057j | |
| dc.relation.ispartof | Inorganic Chemistry, 2014, vol. 53, num. 6, p. 3194-3203 | |
| dc.relation.uri | https://doi.org/10.1021/ic500057j | |
| dc.rights | (c) American Chemical Society , 2014 | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | |
| dc.subject.classification | Lligands | |
| dc.subject.classification | Propietats magnètiques | |
| dc.subject.classification | Teoria quàntica | |
| dc.subject.other | Ligands | |
| dc.subject.other | Magnetic properties | |
| dc.subject.other | Quantum theory | |
| dc.title | New topologies in pentanuclear nickel/oximato clusters: structural and magnetic characterization | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/acceptedVersion |
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