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New topologies in pentanuclear nickel/oximato clusters: structural and magnetic characterization

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dc.contributor.authorEsteban Jarne, Jordi
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.contributor.authorSánchez Costa, José
dc.contributor.authorTeat, Simon J.
dc.contributor.authorEscuer Fité, Albert
dc.date.accessioned2020-06-12T07:04:03Z
dc.date.available2020-06-12T07:04:03Z
dc.date.issued2014
dc.date.updated2020-06-12T07:04:03Z
dc.description.abstractIn the present work, five new Ni5 clusters employing the versatile 2-pyridylcyanoxime ligand have been synthesized and chemically, structurally, and magnetically characterized. The crystallographic examination of these Ni5 clusters together with those already published in the literature, giving a total number of 14 complexes, exhibiting up to 8 different topologies for which the relationship between topology, reaction conditions and magnetic response has been analyzed. DC magnetic measurements were carried in the 300-2 K range for the new complexes and the analysis of the experimental data revealed an antiferromagnetic response for the oximato mediated interactions with a variety of ground states (S = 0, 1, 3) as function of the cluster topology.
dc.format.extent36 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec634889
dc.identifier.issn0020-1669
dc.identifier.urihttps://hdl.handle.net/2445/165286
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/ic500057j
dc.relation.ispartofInorganic Chemistry, 2014, vol. 53, num. 6, p. 3194-3203
dc.relation.urihttps://doi.org/10.1021/ic500057j
dc.rights(c) American Chemical Society , 2014
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.subject.classificationLligands
dc.subject.classificationPropietats magnètiques
dc.subject.classificationTeoria quàntica
dc.subject.otherLigands
dc.subject.otherMagnetic properties
dc.subject.otherQuantum theory
dc.titleNew topologies in pentanuclear nickel/oximato clusters: structural and magnetic characterization
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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