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Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/125848
A new trinuclear N-N bridged Cu(II) complex with an asymmetric Schiff base ligand derived from hydrazine
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In this paper we report the synthesis of an asymmetric Schiff base ligand derived from hydrazine and its Cu(II) trinuclear coordination complex, [Cu-3(HYDRAV)(2)CI2] (HYDRAV-Cu). The ligand HYDRAVH(2) and the Cu(II) complex HYDRAV-Cu have been crystallographically characterized. HYDRAVH(2) contains a fluorescent naphthyl group and emission properties of both HYDRAVH(2) and HYDRAV-Cu are reported. The magnetic properties of HYDRAV-Cu have been investigated. Hydrazine is an excellent precursor for asymmetric Schiff base ligands that afford antiferromagnetic coupling as shown here for HYDRAV-Cu. (C) 2017 Elsevier Ltd. All rights reserved.
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GHOLIZADEH DOGAHEH, Samira, KHANMOHAMMADI, Hamid and SAÑUDO ZOTES, Eva Carolina. A new trinuclear N-N bridged Cu(II) complex with an asymmetric Schiff base ligand derived from hydrazine. Polyhedron. 2017. Vol. 133, num. 48-53. ISSN 0277-5387. [consulted: 8 of September of 2026]. Available at: https://hdl.handle.net/2445/125848