A new trinuclear N-N bridged Cu(II) complex with an asymmetric Schiff base ligand derived from hydrazine

dc.contributor.authorGholizadeh Dogaheh, Samira
dc.contributor.authorKhanmohammadi, Hamid
dc.contributor.authorSañudo Zotes, Eva Carolina
dc.date.accessioned2018-11-05T15:04:38Z
dc.date.available2019-09-05T05:10:15Z
dc.date.issued2017-09-05
dc.date.updated2018-11-05T15:04:38Z
dc.description.abstractIn this paper we report the synthesis of an asymmetric Schiff base ligand derived from hydrazine and its Cu(II) trinuclear coordination complex, [Cu-3(HYDRAV)(2)CI2] (HYDRAV-Cu). The ligand HYDRAVH(2) and the Cu(II) complex HYDRAV-Cu have been crystallographically characterized. HYDRAVH(2) contains a fluorescent naphthyl group and emission properties of both HYDRAVH(2) and HYDRAV-Cu are reported. The magnetic properties of HYDRAV-Cu have been investigated. Hydrazine is an excellent precursor for asymmetric Schiff base ligands that afford antiferromagnetic coupling as shown here for HYDRAV-Cu. (C) 2017 Elsevier Ltd. All rights reserved.
dc.format.extent6 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec674321
dc.identifier.issn0277-5387
dc.identifier.urihttps://hdl.handle.net/2445/125848
dc.language.isoeng
dc.publisherElsevier Ltd
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1016/j.poly.2017.05.010
dc.relation.ispartofPolyhedron, 2017, vol. 133, p. 48-53
dc.relation.urihttps://doi.org/10.1016/j.poly.2017.05.010
dc.rightscc-by-nc-nd (c) Elsevier Ltd, 2017
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationPropietats magnètiques
dc.subject.classificationLligands (Bioquímica)
dc.subject.otherMagnetic properties
dc.subject.otherLigands (Biochemistry)
dc.titleA new trinuclear N-N bridged Cu(II) complex with an asymmetric Schiff base ligand derived from hydrazine
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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