A new trinuclear N-N bridged Cu(II) complex with an asymmetric Schiff base ligand derived from hydrazine
| dc.contributor.author | Gholizadeh Dogaheh, Samira | |
| dc.contributor.author | Khanmohammadi, Hamid | |
| dc.contributor.author | Sañudo Zotes, Eva Carolina | |
| dc.date.accessioned | 2018-11-05T15:04:38Z | |
| dc.date.available | 2019-09-05T05:10:15Z | |
| dc.date.issued | 2017-09-05 | |
| dc.date.updated | 2018-11-05T15:04:38Z | |
| dc.description.abstract | In this paper we report the synthesis of an asymmetric Schiff base ligand derived from hydrazine and its Cu(II) trinuclear coordination complex, [Cu-3(HYDRAV)(2)CI2] (HYDRAV-Cu). The ligand HYDRAVH(2) and the Cu(II) complex HYDRAV-Cu have been crystallographically characterized. HYDRAVH(2) contains a fluorescent naphthyl group and emission properties of both HYDRAVH(2) and HYDRAV-Cu are reported. The magnetic properties of HYDRAV-Cu have been investigated. Hydrazine is an excellent precursor for asymmetric Schiff base ligands that afford antiferromagnetic coupling as shown here for HYDRAV-Cu. (C) 2017 Elsevier Ltd. All rights reserved. | |
| dc.format.extent | 6 p. | |
| dc.format.mimetype | application/pdf | |
| dc.identifier.idgrec | 674321 | |
| dc.identifier.issn | 0277-5387 | |
| dc.identifier.uri | https://hdl.handle.net/2445/125848 | |
| dc.language.iso | eng | |
| dc.publisher | Elsevier Ltd | |
| dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2017.05.010 | |
| dc.relation.ispartof | Polyhedron, 2017, vol. 133, p. 48-53 | |
| dc.relation.uri | https://doi.org/10.1016/j.poly.2017.05.010 | |
| dc.rights | cc-by-nc-nd (c) Elsevier Ltd, 2017 | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | |
| dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | |
| dc.subject.classification | Propietats magnètiques | |
| dc.subject.classification | Lligands (Bioquímica) | |
| dc.subject.other | Magnetic properties | |
| dc.subject.other | Ligands (Biochemistry) | |
| dc.title | A new trinuclear N-N bridged Cu(II) complex with an asymmetric Schiff base ligand derived from hydrazine | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/acceptedVersion |
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