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Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/163457
Preparation, spectroscopic and structural study of copper(II) complexes derived from bulky pyridine ligands
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Three different binuclear tetracarboxylato-bridged copper(II) complexes supported by bulky pyridines ligands [Cu(m-MeCO2)2(dPy)]2 (dPy = 3-phenylpyridine (1), 2-benzylpyridine (2) and 4-acetylpyridine (3)) have been synthesised. These compounds were obtained from reaction of [Cu(MeCO2)2(H2O)]2 with pyridine-derived ligands in methanol at room temperature. All compounds were fully characterized by analytical and spectroscopic methods. The molecular structures were determined by X-ray diffraction analysis. All compounds consist of binuclear units where both Cu(II) atoms are linked by four syn-syn carboxylates bridges, showing a paddle-wheel unit, and exhibit interesting intermolecular interactions in the outer coordination sphere.
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GUERRERO, Miguel, AYLLÓN, J. a., CALVET PALLÀS, Maria teresa, BARDIA, Ma. mercedes, PONS, Josefina. Preparation, spectroscopic and structural study of copper(II) complexes derived from bulky pyridine ligands. _Polyhedron_. 2017. Vol. 134, núm. 107-113. [consulta: 5 de març de 2026]. ISSN: 0277-5387. [Disponible a: https://hdl.handle.net/2445/163457]