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2023-08-02

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cc-by (c) L. A. Barrios et al., 2023
Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/217014

A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest

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https://doi.org/10.1039/d3cc02278a

Abstract

A biphenyl-spaced bis-pyrazolylpyridine ligand interacts with ferrous ions to engender a dimetallic helical coordination cage that encapsulates an Fe3+ tris-anilate complex. The host–guest interaction breaks the symmetry of the Fe2+ centers causing a differential spin crossover behavior in them that can be followed in great detail crystallographically.

Subject

Òxids, Ferro, Química supramolecular

Subject (English)

Oxides, Iron, Supramolecular chemistry

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Articles publicats en revistes (Química Inorgànica i Orgànica)

Citation

BARRIOS MORENO, Leoní Alejandra, et al. A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest. Chemical Communications. 2023. Vol. 59, num. 10628-10631. ISSN 1359-7345. [consulted: 15 of June of 2026]. Available at: https://hdl.handle.net/2445/217014

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