A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest

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dc.contributor.authorBarrios Moreno, Leoní Alejandra
dc.contributor.authorTeat, Simon J.
dc.contributor.authorRoubeau, Olivier
dc.contributor.authorAromí Bedmar, Guillem
dc.date.accessioned2024-12-11T09:19:54Z
dc.date.available2024-12-11T09:19:54Z
dc.date.issued2023-08-02
dc.date.updated2024-12-11T09:19:54Z
dc.description.abstractA biphenyl-spaced bis-pyrazolylpyridine ligand interacts with ferrous ions to engender a dimetallic helical coordination cage that encapsulates an Fe3+ tris-anilate complex. The host–guest interaction breaks the symmetry of the Fe2+ centers causing a differential spin crossover behavior in them that can be followed in great detail crystallographically.
dc.format.extent4 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec739859
dc.identifier.issn1359-7345
dc.identifier.urihttps://hdl.handle.net/2445/217014
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofReproducció del document publicat a: https://doi.org/10.1039/d3cc02278a
dc.relation.ispartofChemical Communications, 2023, vol. 59, p. 10628-10631
dc.relation.urihttps://doi.org/10.1039/d3cc02278a
dc.rightscc-by (c) L. A. Barrios et al., 2023
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationÒxids
dc.subject.classificationFerro
dc.subject.classificationQuímica supramolecular
dc.subject.otherOxides
dc.subject.otherIron
dc.subject.otherSupramolecular chemistry
dc.titleA supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion

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