Files
Document type
ArticleVersion
Accepted versionPublication date
All rights reserved
Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/163458
Zn(II) and Cd(II) Coordination Dimers Based on Mixed Benzodioxole-Carboxylate and N-Donor Ligands: Synthesis, Characterization, Crystal Structures and Photoluminescence Properties
Journal Title
Director/Tutor
Journal ISSN
Volume Title
Related resource
Abstract
Four new compounds, formulated as [Zn(m-Pip)2(3-Phpy)]2 (1), [Zn(m-Pip)2(4-Phpy)]2 (2), [Cd(m-Pip)(Pip)(3-Phpy)2]2 (3) and [Cd(m-Pip)(Pip)(4-Phpy)2]2 (4) (HPip=1,3-benzodioxole-5-carboxylic acid; Phpy= phenylpyridine), have been successfully assembled based on rigid carboxylate/pyridine ligands. These four compounds have been fully characterized by analytical and spectroscopic methods. The aim of the present study is to investigate the structural effect and the influence of the size of metal on the class, geometry and type of coordination of the carboxylate ligands (syn-syn, syn-anti) in the final 3D-arrangements of the structures. Finally, luminescence properties of these new four coordination dimers have been investigated.
Subject
Subject (English)
Citation
Citation
GUERRERO, Miguel, et al. Zn(II) and Cd(II) Coordination Dimers Based on Mixed Benzodioxole-Carboxylate and N-Donor Ligands: Synthesis, Characterization, Crystal Structures and Photoluminescence Properties. Chemistryselect. 2017. Vol. 2, num. 2, pags. 632-639. ISSN 2365-6549. [consulted: 17 of June of 2026]. Available at: https://hdl.handle.net/2445/163458