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Article

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Accepted version

Publication date

2020-12-23

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/185030

Metal-Organic Nanocapsules with Functionalized s-Heptazine Ligands

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https://doi.org/10.1021/acs.inorgchem.0c03631

Abstract

A metalloorganic capsule was synthesized where the ligand is a derivative of heptazine with three carboxylic groups that are coordinated to CuII cations, forming paddle-wheel motifs. Each nanocapsule is neutral, with 12 CuII centers and 8 ligands adopting a rhombicuboctahedron shape. It has almost 3 nm diameter, and the main intermolecular interactions in the solid are π··· π stacking between the C6N7 heptazine moieties. The nanocapsules can form monolayers deposited on graphite as observed by atomic force microscopy, which confirms their stability in solution.

Subject

Lligands, Molècules, Nanociència

Subject (English)

Ligands, Molecules, Nanoscience

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Articles publicats en revistes (Química Inorgànica i Orgànica)
Articles publicats en revistes (Institut de Química Teòrica i Computacional (IQTCUB))

Citation

MAXWELL VILLACORTA, Lindley Andrés, et al. Metal-Organic Nanocapsules with Functionalized s-Heptazine Ligands. Inorganic Chemistry. 2020. Vol. 60, num. 2, pags. 570-573. ISSN 0020-1669. [consulted: 8 of June of 2026]. Available at: https://hdl.handle.net/2445/185030

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