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Metal-Organic Nanocapsules with Functionalized s-Heptazine Ligands

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dc.contributor.authorMaxwell Villacorta, Lindley Andrés
dc.contributor.authorMartinez, Hector
dc.contributor.authorMartin-Rodriguez, Alejandro
dc.contributor.authorGómez Coca, Silvia
dc.contributor.authorRissanen, Kari
dc.contributor.authorRuiz Sabín, Eliseo
dc.date.accessioned2022-04-19T17:27:40Z
dc.date.available2022-04-19T17:27:40Z
dc.date.issued2020-12-23
dc.date.updated2022-04-19T17:27:40Z
dc.description.abstractA metalloorganic capsule was synthesized where the ligand is a derivative of heptazine with three carboxylic groups that are coordinated to CuII cations, forming paddle-wheel motifs. Each nanocapsule is neutral, with 12 CuII centers and 8 ligands adopting a rhombicuboctahedron shape. It has almost 3 nm diameter, and the main intermolecular interactions in the solid are π··· π stacking between the C6N7 heptazine moieties. The nanocapsules can form monolayers deposited on graphite as observed by atomic force microscopy, which confirms their stability in solution.
dc.format.extent4 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec709223
dc.identifier.issn0020-1669
dc.identifier.urihttps://hdl.handle.net/2445/185030
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.0c03631
dc.relation.ispartofInorganic Chemistry, 2020, vol. 60, num. 2, p. 570-573
dc.relation.urihttps://doi.org/10.1021/acs.inorgchem.0c03631
dc.rights(c) American Chemical Society , 2020
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationLligands
dc.subject.classificationMolècules
dc.subject.classificationNanociència
dc.subject.otherLigands
dc.subject.otherMolecules
dc.subject.otherNanoscience
dc.titleMetal-Organic Nanocapsules with Functionalized s-Heptazine Ligands
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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