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2018-02-05

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/162699

Triple Halide Bridges in Chiral (Mn2Mn6Na2I)-Mn-II-Na-III Cages: Structural and Magnetic Characterization

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https://doi.org/10.1021/acs.inorgchem.7b03125

Abstract

A family of decanuclear chiral clusters with a (Mn2Mn6Na2I)-Mn-II-Na-III core have been synthesized from enantiomerically pure Schiff bases. The new systems consist of two (Mn2Mn6Na2I)-Mn-II-Na-III units linked by rare triple chloro or bromo bridges between the divalent Mn cations. Susceptibility measurements point out the weak anti ferromagnetic interaction mediated by these kinds of bridges and afford the first magnetic measurements for the (mu-Br)(3) case.

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Lligands, Propietats magnètiques, Halògens, Cations, Metalls de transició

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Ligands, Magnetic properties, Halogens, Cations, Transition metals

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Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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MAYANS AYATS, Júlia, FONT BARDIA, Ma. Mercedes and ESCUER FITÉ, Albert. Triple Halide Bridges in Chiral (Mn2Mn6Na2I)-Mn-II-Na-III Cages: Structural and Magnetic Characterization. Inorganic Chemistry. 2018. Vol. 57, num. 3, pags. 926-929. ISSN 0020-1669. [consulted: 7 of June of 2026]. Available at: https://hdl.handle.net/2445/162699

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