Triple Halide Bridges in Chiral (Mn2Mn6Na2I)-Mn-II-Na-III Cages: Structural and Magnetic Characterization

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dc.contributor.authorMayans Ayats, Júlia
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.contributor.authorEscuer Fité, Albert
dc.date.accessioned2020-05-27T17:43:38Z
dc.date.available2020-05-27T17:43:38Z
dc.date.issued2018-02-05
dc.date.updated2020-05-27T17:43:38Z
dc.description.abstractA family of decanuclear chiral clusters with a (Mn2Mn6Na2I)-Mn-II-Na-III core have been synthesized from enantiomerically pure Schiff bases. The new systems consist of two (Mn2Mn6Na2I)-Mn-II-Na-III units linked by rare triple chloro or bromo bridges between the divalent Mn cations. Susceptibility measurements point out the weak anti ferromagnetic interaction mediated by these kinds of bridges and afford the first magnetic measurements for the (mu-Br)(3) case.
dc.format.extent18 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec681397
dc.identifier.issn0020-1669
dc.identifier.urihttps://hdl.handle.net/2445/162699
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.7b03125
dc.relation.ispartofInorganic Chemistry, 2018, vol. 57, num. 3, p. 926-929
dc.relation.urihttps://doi.org/10.1021/acs.inorgchem.7b03125
dc.rights(c) American Chemical Society , 2018
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.subject.classificationLligands
dc.subject.classificationPropietats magnètiques
dc.subject.classificationHalògens
dc.subject.classificationCations
dc.subject.classificationMetalls de transició
dc.subject.otherLigands
dc.subject.otherMagnetic properties
dc.subject.otherHalogens
dc.subject.otherCations
dc.subject.otherTransition metals
dc.titleTriple Halide Bridges in Chiral (Mn2Mn6Na2I)-Mn-II-Na-III Cages: Structural and Magnetic Characterization
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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