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Article

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Accepted version

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2012

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/210180

Synthesis and characterization of CoIII3 inverse metallacrowns via use of 6-methyl-2-pyridylaldoxime

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https://doi.org/10.1016/j.inoche.2011.11.037

Abstract

The use of 6-methyl-2-pyridylaldoxime (6-mepaoH) in cobalt carboxylate chemistry has yielded metallacrowns with general formula [CoIII3(μ3-O)(O2CMe)3(6-mepao)3]2[CoII(L)4] (1⋅2MeOH⋅1.5H2O, L=AcO−and 2⋅2.5H2O, L=NCS−). Compounds 1 and 2 display an unusual structural motif in cobalt-oximate chemistry, consisting of CoIII triangles centered by one μ3-oxo ligand. Crystal structure and EPR characterization of CoII anions are reported.

Subject

Química inorgànica, Estructura cristal·lina (Sòlids)

Subject (English)

Inorganic chemistry, Layer structure (Solids)

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Articles publicats en revistes (Química Inorgànica i Orgànica)
Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

Citation

VLAHOPOULOU, Gina, et al. Synthesis and characterization of CoIII3 inverse metallacrowns via use of 6-methyl-2-pyridylaldoxime. Inorganic Chemistry Communications. 2012. Vol. 16, num. 78-80. ISSN 1387-7003. [consulted: 11 of June of 2026]. Available at: https://hdl.handle.net/2445/210180

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