Synthesis and characterization of CoIII3 inverse metallacrowns via use of 6-methyl-2-pyridylaldoxime
| dc.contributor.author | Vlahopoulou, Gina | |
| dc.contributor.author | Escuer Fité, Albert | |
| dc.contributor.author | Font Bardia, Ma. Mercedes | |
| dc.contributor.author | Calvet Pallàs, Maria Teresa | |
| dc.date.accessioned | 2024-04-19T06:18:25Z | |
| dc.date.available | 2024-04-19T06:18:25Z | |
| dc.date.issued | 2012 | |
| dc.date.updated | 2024-04-19T06:18:30Z | |
| dc.description.abstract | The use of 6-methyl-2-pyridylaldoxime (6-mepaoH) in cobalt carboxylate chemistry has yielded metallacrowns with general formula [CoIII3(μ3-O)(O2CMe)3(6-mepao)3]2[CoII(L)4] (1⋅2MeOH⋅1.5H2O, L=AcO−and 2⋅2.5H2O, L=NCS−). Compounds 1 and 2 display an unusual structural motif in cobalt-oximate chemistry, consisting of CoIII triangles centered by one μ3-oxo ligand. Crystal structure and EPR characterization of CoII anions are reported. | |
| dc.format.extent | 16 p. | |
| dc.format.mimetype | application/pdf | |
| dc.identifier.idgrec | 603115 | |
| dc.identifier.issn | 1387-7003 | |
| dc.identifier.uri | https://hdl.handle.net/2445/210180 | |
| dc.language.iso | eng | |
| dc.publisher | Elsevier B.V. | |
| dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.inoche.2011.11.037 | |
| dc.relation.ispartof | Inorganic Chemistry Communications, 2012, vol. 16, p. 78-80 | |
| dc.relation.uri | https://doi.org/10.1016/j.inoche.2011.11.037 | |
| dc.rights | (c) Elsevier B.V., 2012 | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | |
| dc.subject.classification | Química inorgànica | |
| dc.subject.classification | Estructura cristal·lina (Sòlids) | |
| dc.subject.other | Inorganic chemistry | |
| dc.subject.other | Layer structure (Solids) | |
| dc.title | Synthesis and characterization of CoIII3 inverse metallacrowns via use of 6-methyl-2-pyridylaldoxime | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/acceptedVersion |
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