Synthesis and characterization of CoIII3 inverse metallacrowns via use of 6-methyl-2-pyridylaldoxime

dc.contributor.authorVlahopoulou, Gina
dc.contributor.authorEscuer Fité, Albert
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.contributor.authorCalvet Pallàs, Maria Teresa
dc.date.accessioned2024-04-19T06:18:25Z
dc.date.available2024-04-19T06:18:25Z
dc.date.issued2012
dc.date.updated2024-04-19T06:18:30Z
dc.description.abstractThe use of 6-methyl-2-pyridylaldoxime (6-mepaoH) in cobalt carboxylate chemistry has yielded metallacrowns with general formula [CoIII3(μ3-O)(O2CMe)3(6-mepao)3]2[CoII(L)4] (1⋅2MeOH⋅1.5H2O, L=AcO−and 2⋅2.5H2O, L=NCS−). Compounds 1 and 2 display an unusual structural motif in cobalt-oximate chemistry, consisting of CoIII triangles centered by one μ3-oxo ligand. Crystal structure and EPR characterization of CoII anions are reported.
dc.format.extent16 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec603115
dc.identifier.issn1387-7003
dc.identifier.urihttps://hdl.handle.net/2445/210180
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1016/j.inoche.2011.11.037
dc.relation.ispartofInorganic Chemistry Communications, 2012, vol. 16, p. 78-80
dc.relation.urihttps://doi.org/10.1016/j.inoche.2011.11.037
dc.rights(c) Elsevier B.V., 2012
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationQuímica inorgànica
dc.subject.classificationEstructura cristal·lina (Sòlids)
dc.subject.otherInorganic chemistry
dc.subject.otherLayer structure (Solids)
dc.titleSynthesis and characterization of CoIII3 inverse metallacrowns via use of 6-methyl-2-pyridylaldoxime
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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