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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/162560
Lithium cations in a self-assembled electrostatic nanocapsule
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Cascade self-assembly of small components, without the employment of preformed hosts, yielded a {Ni12Li2} nanometric capsule with multiple endo- and exo-guests (water molecules, Li+, and Et3NH+ cations) linked to selective hydrophilic and hydrophobic binding sites of NiII hexanuclear metallamacrocycles. The synthesis was achieved by using (Bu4N)N3 as a starting reagent instead of the conventional sodium azide to selectively introduce the Li+ cations.
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MAYANS AYATS, Júlia, BARDIA, Ma. Mercedes and ESCUER FITÉ, Albert. Lithium cations in a self-assembled electrostatic nanocapsule. Dalton Transactions. 2019. Vol. 43, num. 16158-16161. ISSN 1477-9226. [consulted: 12 of June of 2026]. Available at: https://hdl.handle.net/2445/162560