Avui, dilluns 8 de juny, el Dipòsit Digital no estarà operatiu de 15:00 a 17:00 h per tasques de manteniment. Disculpeu les molèsties.
Hoy, lunes 8 de junio, el Dipòsit Digital no estará operativo de 15:00 a 17:00 h debido a tareas de mantenimiento. Disculpen las molestias.
Today, Monday, Jun 8th, the Digital Repository will be unavailable due to a system update.

Files

690645.pdf (1.68 MB)

Document type

Article

Version

Accepted version

Publication date

2019-04-01

All rights reserved

Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/161979

{Ni4} Cubanes from enantiomerically pure 2-(1-hydroxyethyl)pyridine ligands: supramolecular chirality

Journal Title

Authors

Director/Tutor

Journal ISSN

Volume Title

Related resource

https://doi.org/10.1039/C9DT01026B

Abstract

Homometallic {NiII4} cubane-like clusters with a rare chiral core have been prepared via the employment of enantiomerically pure 2-(1-hydroxyethyl)pyridine (Hmpm). Comparison with the achiral cubanes derived from the related 2-pyridinemethanol (Hpym) ligand reveals drastic structural changes as a consequence of the transfer of chirality from the ligands to the whole structure. Their magnetic properties have been related to the structural features of their cubane-type cores.

Subject

Quiralitat, Magnetisme

Subject (English)

Chirality, Magnetism

Citation

Collections

Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

Citation

MAYANS AYATS, Júlia, et al. {Ni4} Cubanes from enantiomerically pure 2-(1-hydroxyethyl)pyridine ligands: supramolecular chirality. Dalton Transactions. 2019. Vol. 48, num. 28, pags. 10427-10434. ISSN 1477-9226. [consulted: 8 of June of 2026]. Available at: https://hdl.handle.net/2445/161979

Export metadata

JSON - METS

Share record