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{Ni4} Cubanes from enantiomerically pure 2-(1-hydroxyethyl)pyridine ligands: supramolecular chirality

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Homometallic {NiII4} cubane-like clusters with a rare chiral core have been prepared via the employment of enantiomerically pure 2-(1-hydroxyethyl)pyridine (Hmpm). Comparison with the achiral cubanes derived from the related 2-pyridinemethanol (Hpym) ligand reveals drastic structural changes as a consequence of the transfer of chirality from the ligands to the whole structure. Their magnetic properties have been related to the structural features of their cubane-type cores.

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MAYANS AYATS, Júlia, et al. {Ni4} Cubanes from enantiomerically pure 2-(1-hydroxyethyl)pyridine ligands: supramolecular chirality. Dalton Transactions. 2019. Vol. 48, num. 28, pags. 10427-10434. ISSN 1477-9226. [consulted: 27 of June of 2026]. Available at: https://hdl.handle.net/2445/161979

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