{Ni4} Cubanes from enantiomerically pure 2-(1-hydroxyethyl)pyridine ligands: supramolecular chirality

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dc.contributor.authorMayans Ayats, Júlia
dc.contributor.authorAthanasopoulou, Angeliki A.
dc.contributor.authorPham, A.T.
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.contributor.authorMazarakioti, Eleni C.
dc.contributor.authorPilkington, Melanie
dc.contributor.authorStamatatos, T.C.
dc.contributor.authorEscuer Fité, Albert
dc.date.accessioned2020-05-22T06:55:58Z
dc.date.available2020-05-22T06:55:58Z
dc.date.issued2019-04-01
dc.date.updated2020-05-22T06:55:58Z
dc.description.abstractHomometallic {NiII4} cubane-like clusters with a rare chiral core have been prepared via the employment of enantiomerically pure 2-(1-hydroxyethyl)pyridine (Hmpm). Comparison with the achiral cubanes derived from the related 2-pyridinemethanol (Hpym) ligand reveals drastic structural changes as a consequence of the transfer of chirality from the ligands to the whole structure. Their magnetic properties have been related to the structural features of their cubane-type cores.
dc.format.extent26 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec690645
dc.identifier.issn1477-9226
dc.identifier.urihttps://hdl.handle.net/2445/161979
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/C9DT01026B
dc.relation.ispartofDalton Transactions, 2019, vol. 48, num. 28, p. 10427-10434
dc.relation.urihttps://doi.org/10.1039/C9DT01026B
dc.rights(c) Mayans Ayats, Júlia et al., 2019
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.subject.classificationQuiralitat
dc.subject.classificationMagnetisme
dc.subject.otherChirality
dc.subject.otherMagnetism
dc.title{Ni4} Cubanes from enantiomerically pure 2-(1-hydroxyethyl)pyridine ligands: supramolecular chirality
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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